Five-fold symmetry is forbidden in classical crystals
A classical crystal is a periodic tiling — a wallpaper pattern. A theorem from the 19th century says that any wallpaper repeating in two independent directions can only have 2-, 3-, 4-, or 6-fold rotational symmetry. Five-fold is impossible: pentagons cannot tile the plane without gaps. So if you ever saw a material with sharp diffraction spots arranged with 5-fold symmetry, the rulebook said you were hallucinating. The Penrose tiling sidesteps the theorem by refusing to be periodic in the first place — it can have local five-fold order at every scale precisely because it never closes into a repeating cell.